Some
Chemicals with 'Special' hazards:
Note:
this is a selection of items I have come across in a Biology
Department. There undoubtedly are many more items that
deserve special attention in terms of storage or usage.
Suggestions for inclusion are welcome.
Chemical:
|
Possible
Use:
|
Hazard:
|
picric
acid (trinitrophenol)
|
prepare
a histological stain
|
unstable/shock
sensitive/explosion hazard when dry(<30% water);
keep wetted with >30% water
|
2,4-Dinitrophenol
(DNP)
|
pH
indicator,
respiratory inhibitor
|
unstable/shock
sensitive/explosion hazard when dry; keep wetted with
>30% water
|
hydrazine
and derivatives:
(2,4,
dinitrophenyl hydrazine)
|
chemical
assay
|
flammable
solid; may be shock sensitive; explosive; keep wet
(>30% water
|
sodium
dithionite
|
remove
oxygen from solution
|
may
ignite if water is added to powder
|
sodium
azide
|
metabolic
inhibitor; preservative
|
reacts
with lead, copper to form unstable compounds; do not
pour solutions down the drain
http://bifrost.unl.edu/ehs/FactSheets/soazidfs.html
|
benzoyl
peroxide
|
used
to decolorize samples before measuring in a liquid
scintillation counter
|
shock-sensitive
solid
|
perchlorates
(Mg, Na)
|
Mg
perchlorate is used as a drying agent
|
shock-sensitive
solids
|
peroxide
forming compounds: diethyl ether
(not petroleum ether), di-isopropyl ether tetrahydrofuran,
ethylene glycol monomethyl ether (methyl cellosolve),
dioxane
|
organic
solvents
|
peroxides
formed on exposure to air; should regularly dispose
of old bottles (annually or sooner). May explode
on distillation or drying or even the friction from
opening the cap.
http://bifrost.unl.edu/ehs/FactSheets/peroxfs.html
http://www.cshema.labsafety.umaryland.edu/articles/peroxides.htm
|
perchloric
acid
|
digest
organic samples
|
very
strong oxidizer when heated; old bottles may accumulate
shock-sensitive crystals, Do not unscrew cap!
|
hydrofluoric
acid
|
digest
rocks
|
causes
severe skin burns, penetrates skin and can cause death
due to its interaction with calcium. Check links
below:
http://bifrost.unl.edu/ehs/FactSheets/hfacidfs.html
http://www.cshema.labsafety.umaryland.edu/articles/incident%20reports/hf%20incident.htm
|
aluminum
chloride
|
reagent
|
forms
HCl on contact with moisture; bottles may develop
dangerous pressure buildup
|
The hazard notes listed here do not fully
describe all the problems associated with these compounds.
If you work with any of these items or groups, get further
information from the MSDS or from reference texts stored
in CW315A Biological Sciences Building or in the Cameron
library. The links to more detailed information were current
in December 2000.
If you have some of these items and have
no further use for them, consider disposing of them through
the Office of Environmental Health and Safety. See the
topic on Waste
Disposal (due late April 2001) for
details.
revised
December 15, 2000
BGMcC Department of Biological Sciences, University of Alberta
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