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Some Chemicals with 'Special' hazards:

Note: this is a selection of items I have come across in a Biology Department.  There undoubtedly are many more items that deserve special attention in terms of storage or usage. Suggestions for inclusion are welcome.

Chemical:

Possible Use:

Hazard:

picric acid (trinitrophenol)

prepare a histological  stain

unstable/shock sensitive/explosion hazard when dry(<30% water);
keep wetted with >30% water

2,4-Dinitrophenol (DNP)

pH indicator,
respiratory inhibitor

unstable/shock sensitive/explosion hazard when dry; keep wetted with >30% water

hydrazine and derivatives:
(2,4, dinitrophenyl hydrazine)

chemical assay

flammable solid; may be shock sensitive; explosive; keep wet (>30% water

sodium dithionite

remove oxygen from solution

may ignite if water is added  to powder

sodium azide

metabolic inhibitor; preservative

reacts with lead, copper to form unstable compounds; do not pour solutions down the drain
http://bifrost.unl.edu/ehs/FactSheets/soazidfs.html

benzoyl peroxide

used to decolorize samples before measuring in a liquid scintillation counter

shock-sensitive solid

perchlorates (Mg, Na)

Mg perchlorate is used as a drying agent

shock-sensitive solids

peroxide forming compounds:  diethyl ether (not petroleum ether), di-isopropyl ether  tetrahydrofuran, ethylene glycol monomethyl ether (methyl cellosolve), dioxane

organic solvents

peroxides formed on exposure to air; should regularly dispose of old bottles (annually or sooner).  May explode on distillation or drying or even the friction from opening the cap.
http://bifrost.unl.edu/ehs/FactSheets/peroxfs.html

http://www.cshema.labsafety.umaryland.edu/articles/peroxides.htm

perchloric acid

digest organic samples

very strong oxidizer when heated; old bottles may accumulate shock-sensitive crystals, Do not unscrew cap!

hydrofluoric acid

digest rocks

causes severe skin burns, penetrates skin and can cause death due to its interaction with calcium.  Check links below:

http://bifrost.unl.edu/ehs/FactSheets/hfacidfs.html

http://www.cshema.labsafety.umaryland.edu/articles/incident%20reports/hf%20incident.htm

aluminum chloride

reagent

forms HCl on contact with moisture; bottles may develop dangerous pressure buildup

The hazard notes listed here do not fully describe all the problems associated with these compounds.  If you work with any of these items or groups, get further information from the MSDS or from reference texts stored in CW315A Biological Sciences Building or in the Cameron library.  The links to more detailed information were current in December 2000.

If you have some of these items and have no further use for them, consider disposing of them through the Office of Environmental Health and Safety.  See the topic on Waste Disposal (due late April 2001)  for details.

revised December 15, 2000
BGMcC Department of Biological Sciences, University of Alberta

 


© Department of Biological Sciences - 2001  email Safety Officer- Department of Biological Sciences